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H.E. Dr. Francis Chukwuemeka OKEKE, first resident Ambassador of Nigeria to the Holy See, (5th Nov 2012 - 5th August 2015)
Mr Basil Maduka OKOLO, Pioneer Head of Chancery of the Mission/ Minister Counsellor/ Chargé d’Affaires a.i.(10th Dec 2012 - 30th April 2016)
Mrs. ADOYI Onyeche R.S., Pioneer Administrative Attaché I
Mrs.Ijeoma OKPALAUNEGBU, Pioneer Administrative Attaché II/Executive Officer/Archivist